Prussian blue analogue/KB-derived Ni/Co/KB composite as a superior adsorption-catalysis separator modification...

Lithium‑sulfur batteries (LSBs) are gradually replacing conventional lithium-ion batteries (LIBs), credited to their high theoretical capacity, low cost, and non-toxicity. Nevertheless, the substantial capacity degradation caused by the polysulfide shuttling during charging and discharging has seriously hindered the commercialization of LSBs. Separator modification with functionalized carbon materials has been found to catalyze the breakdown of polysulfides, thereby improving the efficiency of LSBs. Herein, we synthesized Ni/Co-PBAs with KB structures to subsequently derive Ni/Co/KB composites by a carbonization process, which were later used as a modifier layer on the barrier in LSBs in order to effectively alleviate the shuttle problem. The capacity of the Ni/Co/KB composite decorated separator is found to be 1032 mAh/g at 0.5 C with a coulombic efficiency closer to 100%. In the long-term cycling capability evaluation, the initial cycle is approximately 802.9 mAh/g at 1 C, while capacity retention after 400 cycles is also 678.8 mAh/g, with a high-capacity retention rate of 84.5%. The potential of these composites as modifying materials for superior LSBs separators is verified by experimental and theoretical methods.