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Published on: November 11, 2013
Iron phosphate hydroxide hydrate as a novel anode material for advanced aqueous full potassium-ion batteries
Chang Li1, Wenjun Deng1, Yibo Li1
1School of Advanced Materials, Peking University Shenzhen Graduate School, Shenzhen 518055, P. R. China. liruisz@pku.edu.cn.
Abstract:
The development of aqueous potassium-ion batteries is limited by the lack of suitable anode materials. Here, a novel anode material, iron phosphate hydroxide hydrate Fe1.19PO4(OH)0.18(H2O)0.3, was introduced and synthesized, which delivers considerable reversible capacities of 80 mA h g-1 at 0.05 A g-1. An aqueous full potassium-ion battery assembled with the K2Zn3(Fe(CN)6)2 cathode exhibits 80% capacity retention after 1000 cycles.
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Ions as Acids and Bases
Salts are ionic compounds composed of cations and anions, either of which may be capable of undergoing an acid or base ionization reaction with water. Aqueous salt solutions, therefore, may be acidic, basic, or neutral, depending on the relative acid-base strengths of the salt’s constituent ions. For example, dissolving the ammonium chloride in water results in its dissociation, as described by the equation:
Electrolysis

