Cesium removal from wastewater: High-efficient and reusable adsorbent K_1.93Ti_0.22Sn₃S_6.43

Efficient and quick removal of radioactive Cs⁺ from wastewater is significant for the safe use of nuclear energy and human health. A novel adsorbent K_1.93Ti_0.22Sn₃S_6.43 (KTSS) was developed for Cs⁺ removal from complex natural water systems. The working mechanism of KTSS for removing Cs⁺ was the synergistic effect of ion exchange and the Cs⋯S binding, which was proved by several characterization techniques. KTSS showed ultrafast kinetics for Cs⁺ adsorption within 1 min with a removal rate of 99%. Meanwhile, KTSS exhibited a higher adsorption capacity of 450.12 mg/g than many other adsorbents to remove Cs⁺ and possessed excellent chemical stability in a wide pH range of 3-12. Thanks to the natural affinity arising from the S^2- ligands, KTSS displayed excellent selectivity for Cs⁺ even in different complex water systems. The separation factors between Cs⁺ and the coexisting ions of Na⁺, K⁺, Mg²⁺, Ca²⁺ were ranged from 408.61 to 7448.20. Fortunately, by eluting with NaNO₃ the adsorbent could realize the green regeneration and cyclic utilization. Furthermore, it was found that KTSS had tremendous advantages in the removal of Cs⁺ in comparison with the other adsorbents. Consequently, it should be considered that KTSS obtained in this study has great potential in applying ultrafast and high-efficient removal of Cs⁺ from wastewater.