Construction of modified screen-printed graphite electrode for the application in electrochemical detection of sunset...

The current work introduced a novel electrochemical sensor (screen-printed graphite electrode (SPGE) modified with MnO₂ nanorods anchored graphene oxide nanocomposite (MnO₂ NRs/GO) for sensitive determination of sunset yellow. The characterization of MnO₂ NRs/GO nanocomposite synthesized through a simple hydrothermal approach was determined employing varied analytical equipment like Field emission-scanning electron microscopy (FE-SEM), Fourier transform infrared spectroscopy (FT-IR), and X-ray diffraction (XRD). Chronoamperometric measurements, differential pulse voltammetry (DPV), cyclic voltammetry (CV) and linear sweep voltammetry (LSV) were recruited to recognize the electrochemical oxidation of sunset yellow on the MnO₂ NRs/GO/SPGE. The results of CV proved that the as-synthesized MnO₂ NRs/GO nanocomposite has a good electrocatalytic activity toward sunset yellow. The MnO₂ NRs/GO/SPGE electrode under optimized conditions using the DPV possessed a linear response for different concentrations of sunset yellow (between 0.01 and 115.0 μM) with a low limit of detection (LOD) (0.008 μM). Finally, the impressive applicability of this sensor was confirmed via real sample analysis with excellent recoveries (between 97.3 and 104.6%).