Soft Composites Filled with Iron Oxide and Graphite Nanoplatelets under Static and Cyclic Strain for Different...

Simultaneously exhibiting both a magnetic response and piezoelectric energy harvesting in magneto-rheological elastomers (MREs) is a win-win situation in a soft (hardness below 65) composite-based device. In the present work, composites based on iron oxide (Fe₂O₃) were prepared and exhibited a magnetic response; other composites based on the electrically conductive reinforcing nanofiller, graphite nanoplatelets (GNP), were also prepared and exhibited energy generation. A piezoelectric energy-harvesting device based on composites exhibited an impressive voltage of ~10 V and demonstrated a high durability of 0.5 million cycles. These nanofillers were added in room temperature vulcanized silicone rubber (RTV-SR) and their magnetic response and piezoelectric energy generation were studied both in single and hybrid form. The hybrid composite consisted of 10 per hundred parts of rubber (phr) of Fe₂O₃ and 10 phr of GNP. The experimental data show that the compressive modulus of the composites was 1.71 MPa (virgin), 2.73 (GNP), 2.65 MPa (Fe₂O₃), and 3.54 MPa (hybrid). Similarly, the fracture strain of the composites was 89% (virgin), 109% (GNP), 105% (Fe₂O₃), 133% (hybrid). Moreover, cyclic multi-hysteresis tests show that the hybrid composites exhibiting higher mechanical properties had the shortcoming of showing higher dissipation losses. In the end, this work demonstrates a rubber composite that provides an energy-harvesting device with an impressive voltage, high durability, and MREs with high magnetic sensitivity.