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Related Concept Videos

Diamagnetic Shielding of Nuclei: Local Diamagnetic Current01:14

Diamagnetic Shielding of Nuclei: Local Diamagnetic Current

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An applied magnetic field causes the electrons present in the molecule to circulate, setting up a local diamagnetic current within the molecule. The local diamagnetic current arising from circulating sigma-bonding electrons induces a magnetic field, Blocal that opposes the applied magnetic field, B0. The effective magnetic field experienced by these nuclei is given by the difference between the applied and local magnetic fields in a phenomenon called local diamagnetic shielding. Essentially,...
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Epoxy Coatings Containing Modified Graphene for Electromagnetic Shielding.

Marius Gabriel Bontaș1,2, Aurel Diacon1, Ioan Călinescu1

  • 1Faculty of Chemical Engineering and Biotechnologies, University Politehnica Bucharest, Gh. Polizu Street, 011061 Bucharest, Romania.

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|June 24, 2022
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Functionalized graphene enhances epoxy nanocomposites for electromagnetic interference (EMI) shielding. Modified graphene offers improved flexibility and EMI attenuation, suitable for microwave absorbing textile coatings.

Keywords:
flexible epoxy textile coatinggraphene functionalizationradar absorbing materials

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Area of Science:

  • Materials Science
  • Nanotechnology
  • Polymer Science

Background:

  • Graphene's unique properties make it a candidate for electromagnetic interference (EMI) shielding applications.
  • Developing effective EMI shielding materials requires optimizing graphene's compatibility with polymer matrices.
  • Functionalization of graphene is crucial for enhancing its dispersion and performance in nanocomposites.

Purpose of the Study:

  • To functionalize graphene for improved compatibility with epoxy resins.
  • To characterize the electromagnetic interference (EMI) shielding capacity of graphene-epoxy nanocomposites.
  • To evaluate the mechanical and functional properties of modified graphene-based nanocomposites for potential applications.

Main Methods:

  • Graphene functionalization using small molecules and polymers.
  • Synthesis and characterization of graphene-epoxy nanocomposites.
  • Analysis of EMI shielding effectiveness, SEM, micro-CT, magnetic properties, and stress-strain behavior.

Main Results:

  • Thermogravimetric analysis (TGA) and Raman spectroscopy confirmed graphene synthesis with varying layer thicknesses.
  • Unmodified and hexamethylene diamine (HMDA)-modified graphene exhibited superior EMI shielding at 11 GHz.
  • HMDA-modified graphene nanocomposites showed enhanced flexibility with comparable EMI shielding to unmodified graphene.

Conclusions:

  • HMDA functionalization improves graphene dispersion and flexibility in epoxy nanocomposites.
  • The developed nanocomposites offer a practical solution for microwave absorbing (MA) textile coatings.
  • Functionalized graphene holds promise for advanced EMI shielding and flexible electronic applications.