Spontaneous Ammonia Activation Through Coordination-Induced Bond Weakening in Molybdenum Complexes of a Dianionic...

Ammonia oxidation catalyzed by molecular compounds is of current interest as a carbon-free source of dihydrogen. Activation of N-H bonds through coordination to transition metal centers is a key reaction in this process. We report the substantial activation of ammonia via reaction with low-valent molybdenum complexes of a diborate pentadentate ligand system. Spontaneous loss of dihydrogen from (B₂ Pz₄ Py)Mo^II -NH₃ at room temperature to produce the dinuclear μ-nitrido compound (B₂ Pz₄ Py)Mo-N-Mo(B₂ Pz₄ Py) is observed due to substantial N-H bond weakening upon coordination to Mo. Mechanistic details are supported through the experimental observation/characterization of terminal amido, imido and nitrido complexes and density functional theory computations. The generally under-appreciated role of bridging nitrido intermediates is revealed and discussed, providing guidance for further catalyst development for this process.