Electrospray Ionization Tandem Mass Spectrometry and DFT Survey of Copper(I) Ate Complexes Containing Coordinated
Howard Z Ma1, Allan J Canty2, Richard A J O'Hair1
1School of Chemistry and Bio21 Molecular Science and Biotechnology Institute, University of Melbourne, 30 Flemington Road, Parkville, Victoria 3010, Australia.
Abstract:
Copper(I) borohydride ate complexes of the type Cat+[XCu(BH4)]- have been previously postulated as intermediates in the reactions of copper salts with borohydride. Negative ion electrospray ionization of an acetonitrile solution of copper(I) phenylacetylide with a 10-fold excess of sodium borohydride (NaBH4) revealed the formation of a diverse range of mononuclear, dinuclear and trinuclear cuprates with different numbers of BH4-, H- and CN- ligands, the latter likely being formed by abstraction of CN- from the acetonitrile solvent. Collision-induced dissociation was used to examine the fragmentation reactions of the following borohydride containing cuprates: [Cu(H)(BH4)]-, [Cu(BH4)2]-, [Cu(BH4)(CN)]-, [Cu2(H)(BH4)2]-, [Cu2(H)2(BH4)]-, [Cu2(BH4)2(CN)]-, [Cu2(H)(BH4)(CN)]-, [Cu3(H)(BH4)3]-, [Cu3(H)2(BH4)2]-, [Cu3(H)3(BH4)]-, [Cu3(BH4)2(CN)2]-, and [Cu3(H)(BH4)2(CN)]-. In all cases, BH3 loss is observed. For many of the dinuclear and trinuclear complexes cluster fragmentation by loss of CuH was also observed. In the case of [Cu2(H)2(BH4)]- and [Cu3(H)3(BH4)]-, loss of H2 was also observed. DFT calculations were used to explore potential structures of the various borohydride-containing cuprates and to predict the overall reaction energetics for the various fragmentation channels.
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