Design and optimization of an innovative lanthanum/chitosan bead for efficient phosphate removal and study of process...

Presence of excessive phosphorus in surface waters is the main cause for eutrophication. In this study, a lanthanum/chitosan (La/CS) bead was prepared so as to provide a cost-effective solution to the problem. The optimization of bead for the treatment was conducted, leading to the optimal condition: 30 wt% La/CS bead at a dosage of 30 g L^-1 (wet weight). A higher phosphate removal around 90% was obtained in pH 4.0-10.0. Most of uptake occurred in the first 2 h and the equilibrium was reached in about 6 h. Coexisting ions of Cl^-, [Formula: see text] , [Formula: see text] , and [Formula: see text] had negligible effects on the treatment, while the presence of F^- reduced the uptake by 10.39%. The maximum adsorption capacity of 261.1 mg-PO₄·g^-1 (dried weight) at pH 5.0 was achieved, which is much better than many reported La-based adsorbents. The adsorbed phosphate can be effectively recovered with an alkaline solution. A multi-cycle regeneration-reuse study illustrated that the treated water still met the phosphorus discharge standard. The characterization results demonstrated the disappearance of La(OH)₃ and La₂(CO₃)₃ on the bead and the formation of NH₃⁺ … P and La-P groups after the adsorption, indicating the significant roles of ion exchange and electrostatic attraction on the uptake. The excellent performance found in this study clearly indicates that the optimized La/CS bead is promising in the treatment of phosphate and perhaps its recovery for industrial use.