Deciphering the role of LiNO₃ additives in Li-S batteries

The ultrahigh theoretical energy density of lithium-sulfur (Li-S) batteries has attracted intensive research interest. However, most of the long-term cycling performance parameters are strongly dependent on the utilization of the electrolyte, which is considered as an indispensable component in Li-S batteries. Over the past few decades, numerous research studies around LiNO₃ as an electrolyte additive have been carried out and have been confirmed to significantly upgrade the electrochemical performance of Li-S batteries, but the mechanism of performance improvement is still not well-understood. In this minireview, we revisit the controversial issues surrounding LiNO₃ based on recent representative studies, provide a comprehensive understanding of the role of LiNO₃ in the Li-S battery system, and specifically discuss what the panoramic view of the solid electrolyte interface film formed by LiNO₃ on the surface of Li metal anodes looks like. Finally, we present general conclusions and unique insights into the future development of Li-S batteries. This minireview aims to provide a tutorial reference for researchers who are ready to enter or are active in the field of Li-S batteries.