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Updated: Sep 6, 2025
Chemical Synthesis of Porous Barium Titanate Thin Film and Thermal Stabilization of Ferroelectric Phase by Porosity-Induced Strain
Published on: March 27, 2018
Bandgap-engineered ferroelectric single-crystalline NBT-BT based nanocomposites with excellent visible
Hongyuan Xiao1, Jiahuan He1, Xunyu Lu2
1State Key Laboratory of Metal Matrix Composites, School of Materials Science and Engineering Shanghai Jiao Tong University, Shanghai, 200240, China.
Abstract:
Bandgap engineered ferroelectrics exhibit encouraging multi-energy catalytic performance by coupling the piezoelectricity and photoexcitation, which shows immense potential for environmental remediation and fuel production. However, it is challenging to prepare nano single-crystalline ferroelectric piezo-photoelectric with strong visible light absorption ability. Here, Ni mediated NBT-BT(NBT-BNT) single-crystalline nanocubes around 100 nm with considerable visible light absorption were synthesized by a high-temperature hydrothermal method. The mechanism of Ni2+ on the formation of NBT-BT nanocubes was proposed. The catalytic efficiency of NBT-BNT nanocubes is enhanced by decorating carbon quantum dots (CQDs). The RhB can be degraded within 8 min and the hydrogen production rate reaches up to ∼350 μmol g-1h-1 under visible light-ultrasonic condition. Moreover, under the simulated sunlight-ultrasound condition, RhB can be degraded within merely 3 min and a high H2 production rate of ∼747 μmol g-1h-1 is achieved. This work presents a paradigm for preparing ferroelectric single-crystalline nanocatalysts for multi-energy catalytic application.
