Ultra-permeable intercalated metal-induced microporous polymer nano-dots rooted smart membrane for environmental...

Energy efficient CO₂ separation using ultrathin smart membranes must possess efficient permeation performance, higher surface area and hydrostatic stability at industrially relevant high pressures. However, ultrathin membranes are susceptible to lower surface area, plasticization and swelling which reduces the performance at higher pressure under humidified conditions. This paper evaluates the routes for the potential intercalated effect of metal-induced microporous polymers (MMPs) dots into a cellulose-based polymer matrix to enhance promising properties, including the surface area, CO₂ permeation performance, plasticization resistance and hydrostatic stability of ultrathin smart membranes at high pressure. The MMP dots-rooted smart membrane demonstrated 55 nm thickness of ultrathin selective layer with a higher surface of 220 cm². The enhancement of CO₂ permeability from 14.1 to 108.9 Barrer and CO₂/CH₄ ideal selectivity from 11.8 to 31.1 was observed due to the integration of MMP dots into the cellulose polymer. This result could be due to enhancement of nitrogen lone pair electron interactions with CO₂ followed by amines group which improved the CO₂ adsorption on the membrane surface. The MMP dots-rooted membrane demonstrated plasticization resistance up to 26 bar pressure, as compared to a pristine polymer membrane which is a percentage increase of 160% under humidified conditions. The resulting ultrathin smart membrane exhibited stable performance for a duration of 200 h under humidified conditions which confirmed the higher hydrostatic stability of the membrane. These findings confirmed the potential of MMP dots materials for the development of an industrial scale CO₂ separation process using intercalated membranes.