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Revisiting the Dithienophthalimide Building Block: Improved Synthetic Method Yielding New High-Performance Polymer

Lianghui Li1, Fei Meng1, Ming Zhang2

  • 1State Key Laboratory and Institute of Elemento-Organic Chemistry, Haihe Laboratory of Sustainable Chemical Transformations, College of Chemistry, Nankai University, Tianjin, 300071, China.

Angewandte Chemie (International Ed. in English)
|July 5, 2022
PubMed

Keywords:
ChromiumDithienophthalimideDonorPolymerSolar Cells

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[4+2] Cycloaddition of Conjugated Dienes: Diels–Alder Reaction01:16

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The Diels–Alder reaction is an example of a thermal pericyclic reaction between a conjugated diene and an alkene or alkyne, commonly referred to as a dienophile. The reaction involves a concerted movement of six π electrons, four from the diene and two from the dienophile, forming an unsaturated six-membered ring. As a result, these reactions are classified as [4+2] cycloadditions.