Nickel adsorption from waters onto Fe₃O₄/sugar beet pulp nanocomposite

In this study the magnetic nanocomposite material was synthesized with Fe₃O₄ impregnated to sugar beet pulp using chemical precipitation technique. Ni(II) removal performance of magnetic nanocomposite was investigated under different environmental conditions such as contact time, adsorbent dose, pH, initial heavy metal concentration, etc. The experimental studies have shown that, 81.2% Ni(II) removal efficiency was achieved at optimal conditions (25 mg/L initial Ni(II) concentration at 40 minute contact time, 200 rpm shaking speed, 5 g/L nanocomposite dose and pH 6.6). Freundlich and Langmuir isotherm experiments were performed and correlation coefficients were determined as 94.5% and 99.4%, respectively. The maximum adsorption capacity of material was achieved as 9.36 mg/g. These findings indicate that the adsorption that takes place is a monolayer process. The results of the pseudo-second order kinetic model (R² = 0.9947) indicate the chemisorptions process is used for Ni(II) removal using the electrostatic interaction. Thermodynamic studies illustrated that Ni(II) adsorption onto nanocomposite are exothermic and causes a decrease in the entropy. The adsorption of Ni(II) ions is non-spontaneous except for at low temperature and low initial concentrations. Nanocomposite characterization was illuminated with XRD, FT-IR, BET, TGA, TEM, SEM/EDX analysis.