Europium (III) complex-based fluorescent probe for instantaneous, selective, and sensitive detection of phosgene

Phosgene (carbonyl chloride, COCl₂) is a widely used colorless gas in organic synthesis. However, its high toxicity sets a severe potential damage of public safety. As the fluorescence method has the advantages of simple operation and real-time detection of phosgene, it is extremely important to develop a fluorescent phosgene probe for public health and safety. This study aimed to present a simple Eu³⁺ complex (1) with 2-hydroxyl-1H-benzimidazole moiety as a novel phosgene probe. Probe 1 exhibited characteristic emission of Eu³⁺ in CH₃CN solution, which was specifically quenched after encountering phosgene. The change in the solution color from light red to dark could be easily distinguished with the naked eye under a 365 nm ultraviolet lamp. Finally, the test paper with probe 1 was fabricated for effortless, selective, and visual detection of phosgene gas.