Co-doped CeO₂/N-C nanorods as a bifunctional oxygen electrocatalyst and its application in rechargeable Zn-air...

The development of electrocatalysts for both oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) with high-activity and atability still remain great challenges for rechargeable Zn-air batteries. Herein, a new type of Co-doped Ce-N-C bifunctional electrocatalyst has been synthesized through a simple two-step method, which realizes the high dispersion of Co₃O₄on the CeO₂carbon frame and stabilizes its specific surface area. Benefiting from the synergistic interaction between Co₃O₄and CeO₂, the conductivity of the electrocatalyst is improved and the oxygen reduction reaction/oxygen storage properties are promoted. The resultant Co₃O₄-CeO₂@N-C catalyst shows remarkable ORR activity with the high initial potential (E₀ = 0.8 V), the large limiting current density (j_L = 6 mA cm^-2), and a low Tafel slope (81 mV dec^-1). In full cell tests, Co₃O₄-CeO₂@NC as the oxygen electrode exhibites superior charge/discharge capacity and excellent cycle stability. The assembled Zn-air battery achieves a maximum power density of 110 mW cm^-2at a current density of 180 mA cm^-2, and a high specific capacity of 780 mAh g^-1at a discharge current density of 10 mA cm^-2.