Hydrothermal carbonization of alfalfa: role of processing variables on hydrochar properties

Hydrothermal carbonization of alfalfa is a potential way to reuse agricultural waste. However, the effects of hydrothermal conditions on the properties of alfalfa-derived hydrochar are not clear. Herein, this study investigated the impact of different synthesis conditions (e.g., heating temperature, heating time, and solid to liquid ratio) on the formation and properties of hydrochar. Characterization and thermogravimetric analysis results revealed that with the increase of hydrothermal temperature and the extension of time, cellulose in alfalfa broken down more completely, and the number of carbon spheres and the aromatization degree increased, while the functional groups decreased. Furthermore, there was a surge in the carbon content, fixed carbon yield, high heating value, reduced oxygen, and volatile content. Additionally, the enhancement solid-liquid ratio could effectively improve the energy and mass yields. In all, by adjusting the process parameters of hydrochar, cleaner and higher productivity products could be obtained. This study provides theory basis for the production of target hydrochar that is used to soil amendments, adsorbents, and energy sources in the future.