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Published on: August 28, 2017
Hierarchical liquid marbles formed using floating hydrophobic powder and levitating water droplets
Pritam Kumar Roy1, Bernard P Binks2, Shraga Shoval3
1Chemical Engineering Department, Engineering Faculty, Ariel University, P.O.B. 3, 407000 Ariel, Israel.
Hypothesis:
Liquid marbles i.e. droplets coated by hydrophobic particles may be formed not only on the solid substrates but also on the floating layers of hydrophobic powders such as fluorinated fumed silica or polytetrafluoroethylene.
Experiments:
Formation and growth of liquid marbles on fluorinated fumed silica or polytetrafluoroethylene powder floating on a heated water-vapor interface is reported. Marbles emerge from condensation of water droplets levitating above the powder layer.
Findings:
The kinetics of the growth of droplets is reported. Growth of droplets results from three main mechanisms: water condensation, absorption of small droplets and merging of droplets with neighboring ones. Growing droplets are coated with the hydrophobic powder, eventually giving rise to the formation of stable liquid marbles. Formation of hierarchical liquid marbles is reported. Growth of liquid marbles emerging from water condensation follows the linear temporal dependence. A phenomenological model of the liquid marble growth is suggested.
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