Surveying the Synthesis, Optical Properties and Photocatalytic Activity of Cu₃N Nanomaterials

This review addresses the most recent advances in the synthesis approaches, fundamental properties and photocatalytic activity of Cu₃N nanostructures. Herein, the effect of synthesis conditions, such as solvent, temperature, time and precursor on the precipitation of Cu₃N and the formation of secondary phases of Cu and Cu₂O are surveyed, with emphasis on shape and size control. Furthermore, Cu₃N nanostructures possess excellent optical properties, including a narrow bandgap in the range of 0.2 eV-2 eV for visible light absorption. In that regard, understanding the effect of the electronic structure on the bandgap and on the optical properties of Cu₃N is therefore of interest. In fact, the density of states in the d-band of Cu has an influence on the band gap of Cu₃N. Moreover, the potential of Cu₃N nanomaterials for photocatalytic dye-degradation originates from the presence of active sites, i.e., Cu and N vacancies on the surface of the nanoparticles. Plasmonic nanoparticles tend to enhance the efficiency of photocatalytic dye degradation of Cu₃N. Nevertheless, combining them with other potent photocatalysts, such as TiO₂ and MoS_2, augments the efficiency to 99%. Finally, the review concludes with perspectives and future research opportunities for Cu₃N-based nanostructures.