Removal of harmful components from MSWI fly ash as a pretreatment approach to enhance waste recycling

Municipal solid waste incineration (MSWI) fly ash contains many harmful components that may limit its potential for recycling. An effective pretreatment is therefore required before any recycling can be implemented. In this study, the effects of four pretreatment methods (water washing, CO₂-aided washing, CO₃^2--aided washing, and CO₂ and CO₃^2--aided washing) on the extraction behavior of chloride, sulfate, and heavy metals were evaluated. Water washing was found to be effective for the extraction of all easily and moderately soluble Cl-bearing salts, achieving Cl extraction ratios of 88%, 90%, and 96% for ash from Chongqing (CQ), Qingdao (QD), and Tianjin (TJ), respectively. Injection of CO₂ during washing facilitated decomposition of the hardly soluble Cl-bearing salts, increasing the Cl extraction efficiency by 6% for CQ ash and 9% for QD ash. However, for the TJ ash that contained few insoluble Cl-bearing minerals, CO₂ injection decreased the Cl extraction rate. The addition of CO₃^2- had a negative influence on Cl extraction for all ashes, but it slightly promoted sulfate extraction. Despite the high Cl removal rate, only 23-37% of the sulfate and 0.1-12% of heavy metals were removed. Overall, water-based pretreatment, especially CO₂-aided washing, significantly altered the physical, chemical, and mineralogical characteristics of the fly ash, making it more suitable for recycling. Consequently, the blending ratio of the fly ash for cement clinker manufacture increased from 0.2 to 0.3% in the raw ash to 3.5-5.5% in the treated ash, enabling the extensive use of ash materials.