Fabrication of nanocomposite MoC-Mo2C@C/Cd0.5Zn0.5S: promoted electron migration and improved photocatalytic hydrogen
Tingting Wei1,2, Tingting Zhang1, Zhanbin Jin1,2
1Key Laboratory of Polyoxometalates and Reticular Material Chemistry of Ministry of Education, College of Chemistry, Northeast Normal University, Changchun 130024, P. R. China. weitt321@nenu.edu.cn.
Abstract:
In this work, we successfully prepared composites of carbon-modified in-phase MoC-Mo2C (MoC-Mo2C@C, MMC) nanosheets with Cd0.5Zn0.5S (ZCS) nanorods. The loading of MMC nanosheets significantly improved the hydrogen production rate of ZCS nanorods. The results showed that the photocatalytic hydrogen production rate of ZCS is the highest when MMC nanosheets are 1 wt% of ZCS nanorods (1-MMC/ZCS), reaching 68.8 mmol h-1 g-1, which is 7.7 times that of pure ZCS nanorods. The 1-MMC/ZCS photocatalyst was measured with Na2S/Na2SO3 as a hole sacrifice reagent under irradiation with 420 nm monochromatic light, and the quantum efficiency of 1-MMC/ZCS was 32.9%. The carbon layer can promote the rapid transfer of photogenerated electrons, and in-phase Mo2C-MoC as the active site can synergistically improve the photocatalytic hydrogen production rate of ZCS. Most Mo2C-based materials are still used in the field of electrocatalysis. This study provides a new idea for exploring new molybdenum-based co-catalyst materials in the field of visible light catalytic hydrogen production.
