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Ionic Bonding and Electron Transfer02:48

Ionic Bonding and Electron Transfer

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Ions are atoms or molecules bearing an electrical charge. A cation (a positive ion) forms when a neutral atom loses one or more electrons from its valence shell, and an anion (a negative ion) forms when a neutral atom gains one or more electrons in its valence shell. Compounds composed of ions are called ionic compounds (or salts), and their constituent ions are held together by ionic bonds: electrostatic forces of attraction between oppositely charged cations and anions. 
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Updated: Sep 5, 2025

Solid-state Graft Copolymer Electrolytes for Lithium Battery Applications
05:33

Solid-state Graft Copolymer Electrolytes for Lithium Battery Applications

Published on: August 12, 2013

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Ionic-electronic dual-conductive polymer modified LiCoO2 cathodes for solid lithium batteries.

Mengyang Jia1, Zhijie Bi1, Xiangxin Guo1

  • 1College of Physics, Qingdao University, Ningxia Road, Qingdao, 266071, P. R. China. xxguo@qdu.edu.cn.

Chemical Communications (Cambridge, England)
|July 12, 2022
PubMed
Summary
This summary is machine-generated.

Researchers developed a dual-conductive polymer to enhance lithium batteries. This modification improves cathode stability and conductivity, leading to high capacity retention over 200 cycles for solid lithium batteries.

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Area of Science:

  • Materials Science
  • Electrochemistry
  • Polymer Science

Background:

  • Solid lithium batteries offer enhanced safety over liquid electrolyte counterparts.
  • Modifying cathode materials is crucial for improving battery performance and cycle life.
  • Developing efficient conductive additives is key for advanced battery designs.

Purpose of the Study:

  • To investigate the use of an ionic-electronic dual-conductive polymer for modifying lithium cobalt oxide (LiCoO2) cathodes.
  • To enhance the electrochemical performance and stability of solid lithium batteries.
  • To establish a uniform and fast conductive network within the cathode structure.

Main Methods:

  • Fabrication of a dual-conductive polymer by doping polyethylene glycol into polyaniline.
  • Modification of LiCoO2 cathode materials with the synthesized polymer.
  • Electrochemical testing of the modified cathodes in solid lithium batteries, including cycle stability analysis.

Main Results:

  • The dual-conductive polymer forms uniform and fast conductive networks in the LiCoO2 cathodes.
  • The polymer effectively stabilizes the generation of cathode interface layers.
  • The modified solid lithium battery cells demonstrate high cycle stability, retaining 91.8% of their capacity after 200 cycles.

Conclusions:

  • The ionic-electronic dual-conductive polymer is a promising material for enhancing LiCoO2 cathodes in solid lithium batteries.
  • This polymer modification strategy significantly improves cycle stability and electrode conductivity.
  • The findings pave the way for developing more robust and long-lasting solid-state energy storage devices.