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Solvent-Dependent Oxidative Addition and Reductive Elimination of H2 Across a Gallium-Zinc Bond
Louis J Morris1,2, Thayalan Rajeshkumar3, Akira Okumura1
1Institute for Inorganic Chemistry, RWTH Aachen University, 52062, Aachen, Germany.
Abstract:
H2 adds reversibly across the metal-metal bond of [(BDI)Ga(H)-Zn(tmeda)(thf)][BAr4 F ] (BDI=[HC{C(CH3 )N(2,6-iPr2 -C6 H3 )}2 ]- , TMEDA=N,N,N',N'-tetramethylethylenediamine, BAr4 F- =[B(C6 H3 -3,5-(CF3 )2 )4 ]- ). Due to the stabilising effect of solvent coordination, hydrogenation products [(BDI)GaH2 ] and [(tmeda)ZnH(thf)][BAr4 F ] are favoured in THF solution, but THF-free mixtures of [(BDI)GaH2 ] and [(tmeda)ZnH(OEt2 )][BAr4 F ] are predisposed towards entropically driven dehydrogenation to [(BDI)Ga(H)-Zn(tmeda)][BAr4 F ] in fluorobenzene solution.
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