Electrokinetic geosynthetics restrained nitrogen release from sediment to overlying water through porewater drainage

Porewater is the primary carrier of sediment nitrogen and a crucial source of overlying water nitrogen; its separation thus is essential for restraining nitrogen release from sediment to overlying water. We developed a novel device using electrokinetic geosynthetics to drain porewater with nitrogen and restrain nitrogen release. A batch experiment lasted 1120 h (about 47 days) was conducted with 20 cm depth of overlying water under three conditions, i.e., undrained at 0 V/cm voltage gradient (control), drained at 0 V/cm, and drained at 0.5 V/cm. Under the pulsed direct current, once porewater drained, overlying water replenished sediment pore space and supplied porewater. Along with porewater drainage, sediment nitrogen concentration was reduced by 11%-30%, decreasing nitrogen release from sediment to overlying water from 83 mg/m² in the first 100 h to -95 mg/m² after about 600 h. Processes such as electroosmosis, electromigration, and redox reaction contributed to the restraint on nitrogen release. This research revealed the potentiality of applying electrokinetic geosynthetics to in-situ restraint on sediment nitrogen release in eutrophic waterbodies such as fishponds.