Adsorption of CO₂ by a novel zeolite doped amine modified ternary aerogels

Novel amine functionalized materials can capture greenhouse gas CO₂. In this study, SiO₂-Al₂O₃-ZrO₂ ternary composite aerogel was prepared by sol-gel method, supercritical drying, ultrasonic non-in-situ synthesis and other processes using aluminum chloride hexahydrate as aluminum source, ethyl orthosilicate as silicon source and tetrabbutyl zirconate as zirconium source. The composite material was used as the carrier material. By impregnation method, the modified agent bis - (3-trimethoxy-silpropyl) amine and the composite were fully mixed and modified, and the novel zeolite doped amine functionalized ternary composite aerogel was obtained by doping acidification activation zeolite. The results show that the prepared novel zeolite amine-modified ternary aerogels have rich microporous structure and ordered mesoporous structure. After loading different contents of amine-based materials (CAA-X) in the ternary aerogels, the comparison between CAAZ-X and zeolite amine-modified ternary aerogels is conducted. Zeolite doped CAAZ-30 material shows the best adsorption performance, with a maximum adsorption capacity of 5.30 mmol/g. In the presence of water vapor, CAAZ-30 material also showed the best adsorption performance, with a maximum adsorption capacity of 5.33 mmol/g. This can help us design suitable adsorbent materials for CO₂ capture in different practical applications.