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Cellulose and Pectic Polysaccharides01:15

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 Every plant cell has a cell wall that protects the cell, provides structural support, and gives the cell shape. Cellulose, the main structural component of the plant cell wall, makes up over 30% of plant matter. It is the most abundant organic compound on earth.  Cellulose is an unbranched polysaccharide composed of linear chains of glucose molecules linked by β (1→4) glycosidic bonds.
As a cell matures, its cell wall specializes according to its type. For example, the...
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Towards Biomimicking Wood: Fabricated Free-standing Films of Nanocellulose, Lignin, and a Synthetic Polycation
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Structurally Colored Radiative Cooling Cellulosic Films.

Wenkai Zhu1, Benjamin Droguet2, Qingchen Shen2,3

  • 1School of Mechanical Engineering, Purdue University, West Lafayette, IN, 47906, USA.

Advanced Science (Weinheim, Baden-Wurttemberg, Germany)
|July 17, 2022
PubMed
Summary
This summary is machine-generated.

Researchers developed vibrant, colored daytime radiative cooling (DRC) materials using cellulose nanocrystals. These sustainable films achieve significant cooling while offering aesthetic appeal for broader applications.

Keywords:
celluloseroll-to-roll depositionstructural colorsub-ambient radiative coolingsustainability

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Area of Science:

  • Materials Science
  • Nanotechnology
  • Sustainable Energy

Background:

  • Daytime radiative cooling (DRC) offers sustainable thermal management by radiating heat to space.
  • Current DRC materials are typically white or mirrored, limiting aesthetic applications.
  • Conventional colorants absorb solar radiation, negating cooling benefits.

Purpose of the Study:

  • To develop efficient, colored daytime radiative cooling materials.
  • To overcome the limitations of conventional colorants in DRC applications.
  • To enable aesthetically versatile and sustainable thermal management solutions.

Main Methods:

  • Fabrication of structurally colored films using cellulose nanocrystals (CNCs).
  • Utilizing photonic nanostructures for selective visible light reflection and infrared emission.
  • Employing a porous ethylcellulose (EC) base layer for enhanced broadband solar reflection.
  • Scalable manufacturing via a roll-to-roll process.

Main Results:

  • Achieved sub-ambient daytime cooling of -4 °C and nighttime cooling of -11 °C.
  • Demonstrated vibrant, fade-resistant structural color with low solar absorption (≈3%).
  • Attained high mid-infrared emissivity (>90%) for efficient radiative heat loss.
  • Validated scalable production of colored DRC materials.

Conclusions:

  • Structurally colored cellulose nanocrystal films provide efficient daytime radiative cooling with aesthetic versatility.
  • The developed materials offer a sustainable and scalable solution for advanced thermal management.
  • This approach overcomes the trade-off between color and cooling performance in radiative materials.