Flotation de-inking for recycling paper: contrasting the effects of three mineral oil-free offset printing inks on...

Paper for recycling has become a promising raw material for the pulp and paper industry due to its low cost and because it is conducive to sustainable development. Unfortunately, recycled paper contains a high volume of printed paper that is difficult to deink, which restricts its applications. Flotation deinking plays an essential role in the product quality and process cost of wastepaper recycling. This study was performed to evaluate the deinkability of environmentally friendly offset inks by flotation deinking. For this purpose, three mineral oil free series of four-color inks, namely, hybrid light emitting diode ultraviolet (LED-UV), LED-UV, and vegetable oil-based inks, were printed on white lightweight coated papers under laboratory conditions. The deinking methodology involves repulping, deinking agent treatment, flotation, hand sheet making, and evaluation of the produced hand sheets. The obtained results indicated that the hybrid LED-UV prints had the best deinkability. After flotation deinking, the deinking efficiency and the whiteness of the hybrid LED-UV ink increased by 58.1% and 47.6%, respectively. LED-UV ink had a 46.9% increase in the deinking efficiency and a 37.0% increase in the whiteness of the hand sheet. The deinking efficiency of the vegetable oil-based ink was the lowest, at 42.1%, and the whiteness of the hand sheet increased only by 23.8%. The particle size distribution analysis demonstrated that the hybrid LED-UV four-color ink exhibited a larger value of the average particle size than the two other. Scanning electron microscopy revealed that the hybrid LED-UV ink particles on the surface of the fibers were the least abundant after deinking. The physical strength properties of the hand sheets, including tensile index, folding resistance, and interlayer bonding strength of the hybrid LED-UV, LED-UV inks, and vegetable oil-based inks, increased.