Related Experiment Video
Updated: Sep 4, 2025
Combining Solid-state and Solution-based Techniques: Synthesis and Reactivity of ChalcogenidoplumbatesII or IV
Published on: December 29, 2016
Cyclometalated Platinum(II) Metallomesogens Based on Half-Disc-Shaped β-Diketonate Ligands with Hexacatenar: Crystal
Guo Zou1, Shanrong Zhang1, Shishi Feng1,2
1College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, P. R. China.
Abstract:
A series of new half-disc-shaped platinum(II) complexes [Pt(ppy)(AL-6OCH2)] (Pt-An), [Pt(ppyF)(AL-6OCH2)] (Pt-Bn), and [Pt(ppyCF3)(AL-6OCH2)] (Pt-Cn) (AL-6OCH2 = 1,3-bis(3,4,5-trialkoxyphenyl)propane-1,3-dionato; n = 1, 6, 12) with concise structures have been designed and synthesized, in which 2-phenylpyridine (ppy) derivatives were used as cyclometalated ligands and hexacatenar β-diketonate derivatives AL-6OCH2 as auxiliary ligands. The single-crystal data of the methoxy diketonate analogues Pt-A1, Pt-B1, and Pt-C1 indicate that they all display excellent square planarity. These platinum(II) complexes show a certain emission tunability (ranging from λ = 506-535 nm) by the introduction of fluorine or trifluoromethyl into ppy. Thermal studies reveal that the fluorine-substituted complexes are liquid crystals but the trifluoromethyl-substituted complexes are not. The platinum(II) complexes Pt-A12, Pt-B6, and Pt-B12 can form a hexagonal columnar mesophase via intermolecular π-π interactions. In addition, compared to the reported platinum(II) metallomesogens, Pt-A12 and Pt-B12 exhibit improved ambipolar carrier mobility behaviors in semiconductor devices at the liquid crystal states.
More Related Videos
09:45Accessing Valuable Ligand Supports for Transition Metals: A Modified, Intermediate Scale Preparation of 1,2,3,4,5-Pentamethylcyclopentadiene
Published on: March 20, 2017
12:30Synthesis of a Thiol Building Block for the Crystallization of a Semiconducting Gyroidal Metal-sulfur Framework
Published on: April 9, 2018
Related Concept Videos
02:52Stereoisomerism
Isomers are different chemical species that have the same chemical formula.
Transition metal complexes often exist as geometric isomers, in which the same atoms are connected through the same types of bonds but with differences in their orientation in space. Coordination complexes with two different ligands in the cis and trans positions from a ligand of interest form isomers. For example, the octahedral [Co(NH3)4Cl2]+ ion has two isomers (Figure 1) In the cis...
01:23Properties of Organometallic Compounds
02:58Crystal Field Theory - Octahedral Complexes
To explain the observed behavior of transition metal complexes (such as colors), a model involving electrostatic interactions between the electrons from the ligands and the electrons in the unhybridized d orbitals of the central metal atom has been developed. This electrostatic model is crystal field theory (CFT). It helps to understand, interpret, and predict the colors, magnetic behavior, and some structures of coordination compounds of transition metals.
CFT focuses on...
02:42Valence Bond Theory
02:51Metal-Ligand Bonds
In these complexes, transition metals form coordinate covalent bonds, a kind of Lewis acid-base interaction in which both of the electrons in the bond are contributed by a donor (Lewis base) to an electron acceptor (Lewis acid). The Lewis acid in...
02:46Crystal Field Theory - Tetrahedral and Square Planar Complexes
Crystal field theory (CFT) is applicable to molecules in geometries other than octahedral. In octahedral complexes, the lobes of the dx2−y2 and dz2 orbitals point directly at the ligands. For tetrahedral complexes, the d orbitals remain in place, but with only four ligands located between the axes. None of the orbitals points directly at the tetrahedral ligands. However, the dx2−y2 and dz2 orbitals (along the Cartesian axes) overlap with the ligands less than the dxy,...