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In Situ Transmission Electron Microscopy with Biasing and Fabrication of Asymmetric Crossbars Based on Mixed-Phased a-VOx
Published on: May 13, 2020
Complementary Resistive Switching Behavior in Tetraindolyl Derivative-Based Memory Devices
Surajit Sarkar1, Farhana Yasmin Rahman1, Hritinava Banik1
1Department of Physics, Thin Film and Nanoscience Laboratory, Suryamaninagar, West Tripura, 799022 Agartala, Tripura, India.
Complementary resistive switching (CRS) devices overcome sneak path issues in bipolar resistive switching (BRS) devices. Indole1 molecules demonstrate a temperature-induced transition from BRS to CRS, showing potential for ultradense memory applications.
Area of Science:
- Materials Science
- Condensed Matter Physics
- Device Physics
Background:
- Bipolar resistive switching (BRS) devices suffer from sneak path issues in crossbar arrays.
- Complementary resistive switching (CRS) offers a solution to sneak path problems.
- Indole derivatives are explored for advanced memory applications.
Purpose of the Study:
- To investigate the resistive switching behavior of 1,4-bis(di(1H-indol-3-yl)methyl)benzene (Indole1) molecules.
- To explore the potential of Indole1 for complementary resistive switching (CRS) memory applications.
- To analyze the temperature-induced transition from BRS to CRS in Au/Indole1/ITO devices.
Main Methods:
- Fabrication of Au/Indole1/Indium tin oxide (ITO) devices.
- Characterization of resistive switching properties under varying temperatures (≥353 K).
- Evaluation of memory characteristics including memory window, data retention, stability, and device yield.
Main Results:
- Au/Indole1/ITO devices exhibited bipolar resistive switching (BRS) at ambient conditions.
- A dynamic evolution from BRS to CRS was observed at temperatures of 353 K and higher.
- The CRS mode showed a significant memory window (∼10^3), good data retention (5.1 × 10^3 s), and stability over 50 days with a device yield of ∼60%.
Conclusions:
- Indole1 molecules can facilitate a temperature-triggered transition to complementary resistive switching (CRS).
- The observed CRS behavior with excellent performance metrics suggests potential for ultradense resistive random access memory (RRAM).
- Indole derivatives represent a promising class of materials for future high-density memory technologies.
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