Activation of periodate using ultrasonic waves and UV radiation for landfill leachate treatment

In the present work, saline leachate of the Bushehr coastal city (Iran) was purified using the ultraviolet/ultrasonication wave/periodate process. The initial TDS and TOC values of the leachate studied were 7390 mg/L and 975 mg/L, respectively. During the effect of various parameters on leachate purification, the experiments were optimized at pH 3, oxidizer concentration of 4 mM, and treatment time of 120 min. The initial BOD₅/COD ratio of 0.66 was reduced to 0.42 at the end of the purification time (120 min). After leachate treatment under optimal conditions, the amount of BOD₅, COD, and UV₂₅₄ were 451.5 mg/L, 1072 mg/L, and 12.69 cm^-1, respectively. Concentrations of heavy metals in crude leachate by ICP-OES were checked. Also, the concentration of organic compounds before and after purification was determined using GC-Mass. The leachate purification kinetics followed the first-order model using the designed method. Based on the COD factor, the system energy consumption for leachate treatment was calculated to be 11.4 kWh/m³. The results showed that the system explored (UV/US/IO₄^-) can effectively purify high salinity waste leachate.