A robust, flexible adhesive tape-based SERS substrate fabricated by polymer etching and subsequent Au coating on the...

With the rapid development of trace detection, high-performance flexible surface-enhanced Raman scattering (SERS) substrates have enjoyed steady growth of interest. In this paper, a facile method to improve the robustness of the flexible SERS substrate via the synergistic effect of rigid SiO₂ nanospheres and flexible tape was demonstrated for the first time. In detail, the spin-coated SiO₂ nanosphere monolayer was transferred from the host silicon wafer into the tape by peeling-off process, followed by O₂ plasma etching of tape polymer to expose the nanospheres, and final Au coating to form plentiful SERS "hotspots". The as-prepared SERS sample shows a detection limit of Rhodamine 6G (R6G) down to 10^-10 M and can afford a 500 times bending-releasing cyclic test. Our research provides a promising strategy to prepare robust SERS substrates which exhibit good potential in practical molecule detection on curved surfaces.