Enhancing the Antifouling Ability of a Polyamide Nanofiltration Membrane by Narrowing the Pore Size Distribution via...

Application of nanofiltration membranes in industries still has to contend with membrane fouling that causes a significant loss of separation performance. Herein, an innovative approach to design antifouling membranes with a narrowed pore size distribution by interfacial polymerization (IP) assisted by silane coupling agents is reported. An aqueous solution of piperazine anhydrous (PIP) and γ-(2,3-epoxypropoxy) propytrimethoxysilane (KH560) is employed to perform IP with an organic solution of trimesoyl chloride and tetraethyl orthosilicate (TEOS) on a porous support. In accordance with the results of molecular dynamics and dissipative particle dynamics simulations, the reactive additive KH560 accelerates the diffusion rate of PIP to enrich at the reaction boundary. Moreover, the hydrolysis/condensation of KH560 and TEOS at the aqueous/organic interface forms an interpenetrating network with the polyamide network, which regulates the separation layer structure. The characterization results indicate that the polyamide-silica membrane has a denser, thicker, and uniform separation layer. The mean pore size of the polyamide-silica membrane and the traditional polyamide membrane is 0.62 and 0.74 nm, respectively, and these correspond to the geometric standard deviation (namely, pore size distribution) of 1.39 and 1.97, respectively. It is proved that the narrower pore size distribution endows the polyamide-silica membrane with stronger antifouling performance (flux decay ratio decreases from 18.4 to 3.8%). Such a membrane also has impressive long-term antifouling stability during cane molasses decolorization at a high temperature (50 °C). The outcomes of this study not only provide a novel one-step multiple IP strategy to prepare antifouling nanofiltration membranes but also emphasize the importance of pore size distribution in fouling control for various industrial liquid separations.