Tunable Thermal Switch via Order-Order Transition in Liquid Crystalline Block Copolymer

Organic material-based thermal switch is drawing much attention as one of the key thermal management devices in organic electronic devices. This study aims at tuning the switching temperature (T_S) of thermal conductivity by using liquid crystalline block copolymers (BCs) with different order-order transition temperature (T_tr) related to the types of mesogens in the side chain. The BC films with low T_tr of 363 K and high T_tr of 395 K exhibit reversible thermal conductivity switching behaviors at T_S of ∼360 K and ∼390 K, respectively. The BC films also exhibit thermal conductivity variation originating from the anisotropy of the internal structures: poly(ethylene oxide) domains and liquid crystals. These results demonstrate that the switching behavior is attributed to an order-order transition between BC films with vertically arranged cylinder domains and the ones with ordered sphere domains. This highlights that BCs become a promising thermal conductivity switching material with tailored T_S.