Related Experiment Video
Updated: Sep 3, 2025
Hyperspectral Imaging as a Tool to Study Optical Anisotropy in Lanthanide-Based Molecular Single Crystals
Published on: April 14, 2020
Crystal Growth, Thermal and Spectral Properties of Er: LGGG Crystal
Qiaoyun Chi1, Lei Liu1, Xianhui Xin1
1State Key Laboratory of Crystal Materials, Shandong University, Jinan 250100, China.
Abstract:
A high-quality Er3+-doped (Gd1-xLux)3Ga5O12 (Er: LGGG) laser crystal with a size of Φ 36 × 45 mm3 was successfully grown by the Czochralski (Cz) method for the first time. The effective segregation coefficient of Er3+ was determined to be 0.97, close to 1, and, thus, the uniform high-quality Er: LGGG crystal can be grown. In addition, the thermal and spectroscopic properties of Er: LGGG were investigated. Based on the measured characteristics, the Er: LGGG crystal has a huge potential for use in the 3.0 µm mid-infrared laser because of its outstanding optical quality, extraordinary thermal conductivity and stable structure.
Related Concept Videos
01:25Crystal Growth: Principles of Crystallization
Initiating crystallization involves manipulating the concentration of the solute and the temperature of the solution. Since crystal growth occurs when the ratio of concentration and solubility of the solute in the solvent...
02:18X-ray Crystallography
Diffraction
Diffraction is the change in the direction of travel experienced by an electromagnetic wave when it encounters a physical barrier whose dimensions are comparable to those of the wavelength of the light. X-rays are electromagnetic radiation with wavelengths about as long as the distance between neighboring...
02:46Crystal Field Theory - Tetrahedral and Square Planar Complexes
Crystal field theory (CFT) is applicable to molecules in geometries other than octahedral. In octahedral complexes, the lobes of the dx2−y2 and dz2 orbitals point directly at the ligands. For tetrahedral complexes, the d orbitals remain in place, but with only four ligands located between the axes. None of the orbitals points directly at the tetrahedral ligands. However, the dx2−y2 and dz2 orbitals (along the Cartesian axes) overlap with the ligands less than the dxy,...
02:58Crystal Field Theory - Octahedral Complexes
To explain the observed behavior of transition metal complexes (such as colors), a model involving electrostatic interactions between the electrons from the ligands and the electrons in the unhybridized d orbitals of the central metal atom has been developed. This electrostatic model is crystal field theory (CFT). It helps to understand, interpret, and predict the colors, magnetic behavior, and some structures of coordination compounds of transition metals.
CFT focuses on...