Boosting the Electrocatalytic CO₂ Reduction Reaction by Nanostructured Metal Materials via Defects Engineering

Electrocatalytic CO₂ reduction reaction (CO₂RR) is one of the most effective methods to convert CO₂ into useful fuels. Introducing defects into metal nanostructures can effectively improve the catalytic activity and selectivity towards CO₂RR. This review provides the recent progress on the use of metal nanomaterials with defects towards electrochemical CO₂RR and defects engineering methods. Accompanying these ideas, we introduce the structure of defects characterized by electron microscopy techniques as the characterization and analysis of defects are relatively difficult. Subsequently, we present the intrinsic mechanism of how the defects affect CO₂RR performance. Finally, to promote a wide and deep study in this field, the perspectives and challenges concerning defects engineering in metal nanomaterials towards CO₂RR are put forward.