Potential uses of phosphogypsum: A review

Phosphogypsum (PG) is a by-product of the phosphate fertilizer industry that is produced during the phosphoric acid production process. Annual global PG production ranges between 100 to 300 Mt, with only 15% of that utilized while the rest is usually placed on large dumps with potential serious human and environmental impacts. The aim of this study is to give an overview and to evaluate the existing and potential uses of PG that extend from soil stabilization to cement and chemical industry and for agricultural to geotechnical, human impacts, and environmental applications. More specifically, PG can be used as a substitute in the cement industry, in building materials and in road construction, as a fertilizer for soil improvement, as a raw material for the production of some chemicals, and as a backfilling material for the rehabilitation of abandoned mines and quarries, while the recovery of gypsum and the extraction of rare earth elements signifies the potential importance of PG to cyclic economy. The paper offers an extensive overview of existing and potential uses of PG, discusses their adequacy, and reveals that PG can be widely used under certain conditions, rather than disposed as waste in stockpiles.