Rationally engineering a hierarchical porous carbon and reduced graphene oxide supported magnetite composite with...

Ferric gallate (Fe-GA), an ancient metal-organic framework (MOF) material, has been recently employed as an eco-friendly and cost-effective precursor sample to synthesize a porous carbon confined nano-iron composite (Fe/RPC), and the Fe element in the Fe/RPC sample could be further oxidized to Fe₃O₄ nanocrystals in a 180 °C hydrothermal condition. On this foundation, this work reports an optimized approach to engineering a hierarchical one-dimensional porous carbon and two-dimensional reduced graphene oxide (RGO) supporting framework with Fe₃O₄ nanoparticles well dispersed. Under mild hydrothermal condition, the redox reaction between metal iron atoms from Fe/RPC and surface functional radicals from few-layered graphene oxide sheets (GO) is triggered. As a result, reinforced microstructure and improved atomic efficiency have been achieved for the Fe₃O₄@RPC/RGO sample. The homogeneously dispersed Fe₃O₄ nanoparticles with controlled size are anchored on the surface of the larger sized RGO coating layers while the smaller sized RPC domains are embedded between the RGO sheets as spacer. Challenges including spontaneous aggregation of RPC, over exposure of Fe₃O₄ nanoparticles and excessive restacking of RGO have been significantly inhibited. Furthermore, micro-sized carbon fiber (CF) is chosen as a structural reinforcement additive during electrode fabrication, and the Fe₃O₄@RPC/RGO sample delivers a good specific capacity of 1170.5 mAh·g^-1 under a current rate of 1000 mA·g^-1 for 500 cycles in the half cell form. The reasons for superior electrochemical behaviors have been revealed and the lithium-ion storage performances of the Fe₃O₄@RPC/RGO sample in the full cell form have been preliminarily investigated.