Synthesis and Characterization of a Carbazole-Based Schiff Base Capable of Detection of Al³⁺ in Organic/Aqueous Media

A new fluorescence probe (L) selectively detecting Al³⁺ ions was synthesized via the condensation reaction, and characterized using UV-Vis, FT-IR, ¹H-NMR and ¹³C-NMR spectroscopic techniques. The limit of detection for Al³⁺ ions of this synthesized probe was found to be 9.29 × 10^-7 M, while the Ka constant value was determined to be 1.64 × 10⁴ M^-1. The stoichiometric binding ratio of L-Al³⁺ was found to be 2:1 using the Job's plot method, and this ratio was also confirmed by ¹H-NMR titration and mass spectrometry. The recyclability of the chemosensor was found by the fluorescence method through the addition of EDTA to the L-Al³⁺ solution. The obtained data showed that the carbazole-based Schiff base acted as an ideal chemosensor for Al³⁺. Carbazole-based Schiff base as a fluorescent sensor for detection of Al³⁺ was synthesized and characterized. The association constant (K_a) was calculated to be 1.64 × 10⁴ M^-1 and the limit of detection (LOD) value was determined to be 9.29 × 10^-7 M. It was determined that th Schiff base was bound to Al³⁺ ions in 2:1 stoichiometric ratio. In the presence of other competitive metal cations, the selectivity of sensor L to Al³⁺ was not significantly affected.