Plasmonic Ag-decorated Cu₂O nanowires for boosting photoelectrochemical CO₂ reduction to multi-carbon products

The generation of multi-carbon products on the Cu₂O photocathode remains a great challenge. Herein, effective charge separation and surface catalytic reaction are achieved for photoelectrochemical CO₂ reduction through plasmon metal (Ag) decoration on Cu₂O nanowires. The Cu₂O/Ag composite photocathode achieves a 47.7% faradaic efficiency for CH₃COOH and the generation rate is 212.7 μmol cm^-2 h^-1 under illumination, which is about five times that in dark (44.4 μmol cm^-2 h^-1) at -0.7 V vs. RHE.