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Vicinal or three-bond coupling is commonly observed between protons attached to adjacent carbons. Here, nuclear spin information is primarily transferred via electron spin interactions between adjacent C‑H bond orbitals. This generally favors the antiparallel arrangement of spins, so 3J values are usually positive.
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In bromoethane, the three methyl protons are coupled to the two methylene protons that are three bonds away. In accordance with the n+1 rule, the signal from the methyl protons is split into three peaks with 1:2:1 relative intensities. The methylene protons appear as a quartet, with the relative intensities of 1:3:3:1.
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Spin–Spin Coupling: One-Bond Coupling01:17

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Coupling interactions are strongest between NMR-active nuclei bonded to each other, where spin information can be transmitted directly through the pair of bonding electrons. While nuclei polarize their electrons to the opposite spins, the bonding electron pair has opposite spins. Configurations with antiparallel nuclear spins are expected to be lower in energy. When coupling makes antiparallel states more favorable, J is considered to have a positive value. The one-bond coupling constant, 1J,...
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Two NMR-active nuclei bonded to a central atom can be involved in geminal or two-bond coupling. Geminal coupling is commonly seen between diastereotopic protons in chiral molecules and unsymmetrical alkenes, among others.
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The spin state of an NMR-active nucleus can have a slight effect on its immediate electronic environment. This effect propagates through the intervening bonds and affects the electronic environments of NMR-active nuclei up to three bonds away; occasionally, even farther. This phenomenon is called spin–spin coupling or J-coupling. Coupling interactions are mutual and result in small changes in the absorption frequencies of both nuclei involved. While nuclei of the same element are involved...
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Spin systems where the difference in chemical shifts of the coupled nuclei is greater than ten times J are called first-order spin systems. These nuclei are weakly coupled, and their chemical shifts and coupling constant can generally be estimated from the well-separated signals in the spectrum.
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Area of Science:

  • Condensed Matter Physics
  • Materials Science
  • Spintronics

Background:

  • Van der Waals (vdW) heterostructures with 2D magnets offer atomically sharp interfaces.
  • These interfaces minimize spin-flipping scattering, preserving spin-polarized electronic states.
  • This is crucial for advancing spintronic device functionalities.

Purpose of the Study:

  • To demonstrate electrically tunable spin injection and detection in vdW heterostructures.
  • To investigate the modulation and reversal of spin polarization via electrical bias.
  • To explore the potential for electronic control in next-generation spintronic devices.

Main Methods:

  • Fabrication of vdW heterostructures using ferromagnetic Fe3GeTe2 with hexagonal boron nitride and WSe2.
  • Electrical measurements to assess spin injection and detection efficiency.
  • Application of electrical bias to tune spin polarization and observe magnetoresistance changes.

Main Results:

  • Achieved highly transparent spin injection and detection across vdW interfaces.
  • Demonstrated electrical tunability of net spin polarization, including polarity reversal.
  • Observed sign changes in tunneling magnetoresistance correlated with spin polarization reversals.

Conclusions:

  • Sizable contributions from high-energy localized spin states in the ferromagnet enable spin polarization reversals.
  • The demonstrated tunability of spin-valve operations is a promising route for electronic control.
  • This work paves the way for next-generation low-dimensional spintronic devices.