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Decoding river pollution trends and their landscape determinants in an ecologically fragile karst basin using a
Guoyu Xu1, Hongxiang Fan1, David M Oliver2
1Key Laboratory of Watershed Geographic Sciences, Nanjing Institute of Geography and Limnology, Chinese Academy of Sciences, Nanjing, 210008, China; University of Chinese Academy of Sciences, Beijing, 100049, China.
Machine learning predicts water quality in fragile karst watersheds, identifying agricultural runoff and soil properties as key pollution drivers. This helps target restoration efforts in complex environments.
Area of Science:
- Environmental Science
- Hydrology
- Geochemistry
Background:
- Karst watersheds exhibit complex landscapes influenced by human and natural activities, impacting water quality, nutrient cycling, and contaminant transport.
- Traditional water quality monitoring is limited by cost and labor, restricting spatial assessments, especially in heterogeneous karst regions.
- Geographical catchment characteristics are crucial but often overlooked factors influencing water quality in karst environments.
Purpose of the Study:
- To develop a machine learning model for predicting the spatial distribution of water quality in a fragile karst watershed.
- To identify key determinants of river water quality impairments using interpretable AI methods.
- To support water quality restoration decision-making by providing spatially explicit data.
Main Methods:
- Applied Extreme Gradient Boosting (XGBoost) to predict spatial water quality distribution.
- Utilized Shapley Additive Explanations (SHAP) to interpret model predictions and identify pollutant drivers.
- Evaluated water quality impairment using the Water Quality Damage Index (WQI-DET), focusing on CODMn, TN, and TP.
Main Results:
- The XGBoost model demonstrated strong performance in predicting water quality parameters (CODMn, TN, TP) across the watershed.
- Predicted ranges: CODMn (1.39–17.40 mg/L), TP (0.02–1.31 mg/L), and TN (0.25–5.72 mg/L).
- SHAP analysis identified anthropogenic sources (agriculture), fragile soil properties (low carbon, high permeability), and transport mechanisms (TWI, carbonate rocks) as primary drivers of pollution.
Conclusions:
- Machine learning, specifically XGBoost with SHAP interpretation, effectively predicts and explains spatial water quality variations in karst watersheds.
- Agricultural pollution, soil characteristics, and hydrological factors significantly contribute to water quality impairments in the study area.
- The study provides crucial data and insights for targeted water quality management and policy development in karst regions.
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