Rheological characterization of biofouling layers developing in nanofiltration processes：macroscale rheological...

Nanofiltration (NF) membrane promotes the rapid development of reclaimed water treatment technology. Biofouling significantly limits NF membranes' performance in the case of wastewater treatment. The rheological characteristics of NF biofouling layer and the microfluid field on the vicinity of membrane surface determine the strategies for alleviating biofouling. Here, we tested the biofouling layer generated on NF in a parallel plate rheometer operated in oscillation and stable shear mode, along with shear stress calculation using computational fluid dynamic simulations on the membrane surface. Results indicated that the biofouling layer was typical viscoelastic material, and the yield stress exhibited shear thinning behavior. The biofouling layer tended to show elasticity during long-term operation, and with higher COD content formed, showed stronger elasticity, larger viscosity, and yield stress. Compared with the shear stress on the membrane surface obtained using numerical simulation (0.57 Pa~1.22 Pa), the yield stress (0.59 Pa~266.98 Pa) of NF biofouling layer was relatively large. Our results suggest that the shear stress generated by water flow may not effectively cause formed biofouling layer shedding. The research will provide theoretical and technical support for biofouling control in NF membrane systems and can be applied in advanced wastewater treatment and reclamation processes.