Construction of MIL-125-NH₂@BiVO₄ Composites for Efficient Photocatalytic Dye Degradation

The design and construction of a photocatalyst with a heterostructure are a feasible and effective way to enhance the catalytic performance. Herein, a specially designed composite based on MIL-125-NH₂ and BiVO₄ was prepared and used for wastewater treatment. In the hybrid MIL-125-NH₂@BiVO₄, MIL-125-NH₂ was uniformly dispersed on the BiVO₄ surface. There is a high affinity between MIL-125-NH₂ and BiVO₄ due to the lattice defects. Under visible light irradiation, the catalytic activity of the as-prepared composite was evaluated by the degradation of various dyes such as malachite green, crystal violet, methylene blue, and Congo red. Nearly 98.7, 99.1, and 41.0% of the initial MG, MB and Cr(VI) were respectively removed over the optical sample of BVTN-5, demonstrating that the hybrid holds great promise for practical applications. Moreover, the composites can be recycled and reused with good stability after five consecutive cycles. The mechanism was proposed and discussed in detail. This work will shed light on the construction of MOF-based composites for efficient photocatalysis.