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Construction and Systematical Symmetric Studies of a Series of Supramolecular Clusters with Binary or Ternary Ammonium Triphenylacetates
Published on: February 15, 2016
Synthesis, characterization and antimicrobial property in vitro of supramolecular coordination polymers bearing
Juan Shi1, Fengmin Song1, Hongguang Ge1
1Shaanxi Key Laboratory of Catalysis, School of Chemical & Environmental Sciences, Shaanxi University of Technology, Hanzhong 723001, PR China.
Abstract:
In this study, two supramolecular coordination polymers of Co(II) and Zn(II) based on brominated Schiff base (E)-4-bromo-2-((quinolin-6-ylimino)methyl)phenol (HL) were synthesized and characterized by using elemental analysis, IR spectroscopy and NMR spectroscopy. Furthermore, the crystal structures of HL, CoL2 (І) and ZnL2 (II) were determined by single crystal X-ray analysis. It was revealed that the bromine-related interaction played important role in the self-assembly of HL supramolecular network. The crystal structural investigations revealed that І and II were isomorphous with the same geometry around the metal atom and similar structural feature. The stable four-membered chelate structure resulted from coordination between the metal(II) ion and deprotonated bidentate ligand. And supramolecular coordination polymers of І and II formed diverse architecture through multiple hydrogen bondings, π···π interactions and halogen-related interactions. Antimicrobial activities of polymers were tested toward four bacteria and five phytopathogenic fungi. І and II showed higher activities toward the tested microorganisms than HL. Furthermore, the photoluminescence results indicated that HL and II accompanied with better fluorescence properties in the ultraviolet region.
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