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Coordination effect of citric acid to Ca-deficient hydroxyapatite on phase transition
Daichi Noda1, Iori Yamada1, Kenji Shinozaki2,3
1Department of Materials Science and Technology, Nagaoka University of Technology, Kamitomioka 1603-1, Nagaoka, Niigata 940-2188, Japan. tagaya@mst.nagaokaut.ac.jp.
Abstract:
The phase transition of Ca-deficient hydroxyapatite (CDHA) with citric acid (Cit) coordination was investigated. Cit promoted the substitution of K+ ions into CDHA to generate the HA phase. The K+-doping increased the phase transition temperature of CDHA, providing the transition to β- and α-tricalcium phosphates at higher temperatures. These results suggest controllable phase transition via Cit addition.
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