Remediation of cadmium and lead contaminated soils using Fe-OM based materials

Iron oxide-lignin composites (GLS) were prepared based on the significant role of Fe-OM in the environmental behaviour of heavy metals and lignin binding with iron oxide preferentially in soil. GLS was applied in Cd/Pb immobilization and the stability under acid rain was investigated. The results show that the iron oxide appeared weakly crystalline or amorphous similar to 2-line ferrihydrite after the addition of lignin. Agglomerates of nanoparticles with higher adsorption capacity were observed for GLS. The mobility factor (MF) of Cd/Pb in the soil decreased rapidly after adding GLS. At the 3% dosage, the MF of Cd and Pb in the soil was decreased by 58.94% and 78.15% respectively, which was approximately 5 times that of goethite (GE). The mobile and exchangeable Cd/Pb were converted to organic, amorphous Fe oxide-bound and residue fractions. Under acid rain conditions, MF continues to decline for the GLS group, increasing the organic and amorphous Fe oxide-bound fractions, while for control group (CK) and GE, the trend was the opposite. Lignin could inhibit iron oxide dissolution and stabilize the combination of Cd/Pb and iron oxides in soil. The better stability performance of GLS for Cd/Pb may be related to the higher adsorption capacity and microstructural difference after iron oxide combined with lignin.