Green Synthesis of Silver Nanoparticles Using Spent Coffee Ground Extracts: Process Modelling and Optimization

Large amounts of spent coffee grounds (SCGs) are produced annually worldwide. SCGs contain high levels of phenolics and other bioactive compounds that make them a potential source of reducing and stabilizing agents for the synthesis of metal nanoparticles. This study investigates the use of SCG extracts as a green strategy to produce silver nanoparticles (AgNPs). SCG extracts were obtained using aqueous ethanol as the solvent and then contacted with a silver nitrate solution under the selected conditions. A central composite design coupled with response surface methodology was used to evaluate the effects of solvent composition (C = 30-70% v/v), silver-to-phenolic ratio (R = 3-7 mol/mol), temperature (T = 25-55 °C) and pH (10-12) on the production of AgNPs. Characterization of AgNPs by DLS, TEM and XRD techniques showed that they were highly crystalline with a narrow size distribution. Under optimal reaction conditions, AgNPs with an average size of about 10 nm and a zeta potential of -30.5 to -20.7 mV were obtained. Overall, the results of this study indicate that SCGs are a promising material for the green synthesis of small-sized and stable AgNPs.