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Updated: Sep 1, 2025

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Improving Photoelectrochemical Activity of Magnetron-Sputtered Double-Layer Tungsten Trioxide Photoanodes by
Alshyn Abduvalov1, Marat Kaikanov1, Timur Sh Atabaev2
1Physics Department, School of Sciences and Humanities, Nazarbayev University, Nur-Sultan 010000, Kazakhstan.
Abstract:
The photoelectrochemical (PEC) activity of metal oxide photoelectrodes for water-splitting applications can be boosted in several different ways. In this study, we showed that PEC activity can be significantly improved with a double-layer (crystalline-amorphous) configuration of WO3 thin films irradiated with intense pulsed ion beams (IPIB) of a nanosecond duration. It was found that IPIB irradiation promotes the formation of crystalline and sponge-like WO3 structures on the surface. Due to an increase in the active surface and light scattering in irradiated samples, photocurrent generation increased by ~80% at 1.23 reversible hydrogen electrodes (RHE).
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