Ultrahigh sorption of sulfamethoxazole by potassium hydroxide-modified biochars derived from bean-worm skin waste

Food processing of bean worm generates copious amount of skin as solid waste posing a serious environmental concern. The present study utilized bean worm skin (BWS) waste to produce KOH-modified biochars (KBWS-BCs) for the removal of sulfamethoxazole (SMX) from aqueous solution for the first time. Characterization of KBWS-BCs was systematically investigated via multiple instrumental analysis techniques. The sorption performance of KBWS-BCs as a function of solution pH, reaction time, initial SMX concentration, and reaction temperature was investigated using batch experiments. The classic kinetics and isotherm models were employed to fit the sorption data. KBWS-BCs exhibited large surface areas (3331-4742 m² g^-1) and ultrahigh sorption performance for SMX (maximum adsorption capacities of 909-2000 mg g^-1), which were comparable to those of other modified biochars and even those of well-designed materials. Thermodynamic study indicated that the sorption of SMX on KBWS-BCs was a spontaneous (△G° < 0) and exothermic (△H° < 0) process. Mechanism analysis showed that both chemisorption and physisorption were responsible for the adsorption of SMX by KBWS-BCs. Overall, recycling BWS for preparation of high-performance biochars can be a "win-win" strategy for both disposal of BWS and removal of SMX from wastewater.