Catalytic Upgrading of Biomass-Gasification Mixtures Using Ni-Fe/MgAl₂O₄ as a Bifunctional Catalyst

Biomass gasification streams typically contain a mixture of CO, H₂, CH₄, and CO₂ as the majority components and frequently require conditioning for downstream processes. Herein, we investigate the catalytic upgrading of surrogate biomass gasifiers through the generation of syngas. Seeking a bifunctional system capable of converting CO₂ and CH₄ to CO, a reverse water gas shift (RWGS) catalyst based on Fe/MgAl₂O₄ was decorated with an increasing content of Ni metal and evaluated for producing syngas using different feedstock compositions. This approach proved efficient for gas upgrading, and the incorporation of adequate Ni content increased the CO content by promoting the RWGS and dry reforming of methane (DRM) reactions. The larger CO productivity attained at high temperatures was intimately associated with the generation of FeNi₃ alloys. Among the catalysts' series, Ni-rich catalysts favored the CO productivity in the presence of CH₄, but important carbon deposition processes were noticed. On the contrary, 2Ni-Fe/MgAl₂O₄ resulted in a competitive and cost-effective system delivering large amounts of CO with almost no coke deposits. Overall, the incorporation of a suitable realistic application for valorization of variable composition of biomass-gasification derived mixtures obtaining a syngas-rich stream thus opens new routes for biosyngas production and upgrading.